1-(2-Chlorophenyl)-3-(2-ethylhexanoyl)thiourea

Abstract

In the title compound, C15H21ClN2OS, the central chromophore moiety (C2N2OS) is approximately planar, with a maximum deviation of -0.027 (1) Å, and is oriented at a dihedral angle of 86.7 (1)° with respect to the chlorophenyl ring. An intramolecular N - H⋯O hydrogen bond stabilizes the molecular conformation. In the crystal, molecules associate via N - H⋯S hydrogen bonds, forming inversion dimers with motif R 22(8). These dimers are further connected by N - H⋯O hydrogen bonds, forming R22(12) dimers. As a result, hydrogen-bonded chains running along [110] are formed. C - H⋯S interactions also occur. The terminal two C atoms of the butyl chain are disordered over two positions with an occupancy ratio of 0.54:0.46. Show more