N-(3-Chloropropionyl)-N'-phenylthiourea

Abstract

The title compound, C10H11ClN2OS, adopts a cis-trans configuration with respect to the position of the phenyl and 3-chloro-propionyl groups relative to the thiono group across the C - N bonds. The benzene ring is perpendicular to the propionyl thio-urea fragment with a dihedral angle of 82.62 (10)°. An intra-molecular N - H⋯O inter-action occurs. The crystal structure is stabilized by inter-molecular N - H⋯S hydrogen bonds, which link pairs of mol-ecules, building up R 22(8) ring motifs, and C - H. π inter-actions. Show more