Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride

Abstract

The title compound, [C7H10N3S 2]+-Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS - moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b. Show more