[(L n )Ru{η 3 -(tpdt)}] complexes as dithiolate donors to group 10 metal centers: Synthetic, single-crystal X-ray diffraction and electrochemical studies {L n  = η 6 -C 6 Me 6  (HMB) and η 5 -C 5 Me 5  (Cp*); tpdt = S(CH 2 CH 2 S) 2 }

Shin, Richard; Tan, Geok Kheng; Koh, Lip; Goh, Lai Yoong; Webster, Richard

[(L n )Ru{η 3 -(tpdt)}] complexes as dithiolate donors to group 10 metal centers: Synthetic, single-crystal X-ray diffraction and electrochemical studies {L n = η 6 -C 6 Me 6 (HMB) and η 5 -C 5 Me 5 (Cp*); tpdt = S(CH 2 CH 2 S) 2 }

Date

2004

Authors

Shin, Richard

Tan, Geok Kheng

Koh, Lip

Goh, Lai Yoong

Webster, Richard

Publisher

American Chemical Society

Abstract

Trinuclear mixed metal cationic complexes of Ru-Pd, [{(L n)Ru(μ-η 2:η 3-tpdt)} 2Pd] 2+ (4A, L n = HMB; 8, L n = Cp*), and of Ru-Pt, [{(L n)Ru(μ-η 2: η 3-tpdt)} 2Pd] 2+ (5B, L n = HMB; 9, L n = Cp*), containing bare bridging M(II) (M = Pd, Pt) center