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The inherent displacive structural flexibility of MxV2O5 framework structures

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Date

2000

Authors

Withers, Raymond
Millet, P
Tabira, Y.

Journal Title

Journal ISSN

Volume Title

Publisher

R Oldenbourg Verlag

Abstract

A Rigid Unit Mode (RUM) approach is used to investigate the inherent displacive structural flexibility of layered and tunnel M(x)V2O5 framework structures. Characteristic low energy modes of distortion of these frame-work structures are identified which do not distort the essentially rigid constituent polyhedral units and which enable the framework structures to respond to the local crystal chemistry i.e. to the presence (or absence), as well as positioning, of a range of intercalating cations.

Description

Keywords

Keywords: cation; intercalating agent; vanadium; vanadium derivative; article; concentration response; crystal structure; energy; molecular stability; stoichiometry; structure analysis

Citation

URI

http://hdl.handle.net/1885/25358

Collections

Open Access Research

Source

Zeitschrift fur Kristallographie

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

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