Test environment running 7.6.6

Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Mono-olefin Complexes of the Group VI Metal Carbonyls

Thumbnail Image

Date

1965-07-01

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

o-Allylphenyldiphenylphosphine, o-CH4CH.CH4-C[Formula omitted]H[Formula omitted]PPh[Formula omitted], reacts with Group VI metal di-olefin carbonyls to give stable, chelate complexes (ligand) M (CO)4 (M = Cr, Mo or W), in which the ligand has isomerised to o-propenylphenyldiphenylphosphine, o-CH3-CH:CH-C6H4-PPh2. These are the first mono-olefin complexes of the three Group VI metals. Infrared spectral measurements suggest that coordination of the double bond is strongest in the case of tungsten.

Description

Keywords

Citation

URI

https://dspace-test.anu.edu.au/handle/1885/733723955

Collections

DevOps Pure Testing

Source

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Type

Article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1515/znb-1965-0705

Restricted until

DSpace software copyright © 2002-2026 LYRASIS