Bis[di-2-pyridyl(hydroxy)methanolato-κ 3O,N,N′]-iron(I) tetrafluoroborate trihydrate

Onggo, Djulia; Mimin, Aminah; Yamin, Bohari M.; Ng, Seik Weng

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Bis[di-2-pyridyl(hydroxy)methanolato-κ 3O,N,N′]-iron(I) tetrafluoroborate trihydrate

Date

2005

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Abstract

The crystal structure of the title compound, [Fe(C11H 9-O2N2)2]BF 4·3H2O, contains two independent bis[di-2-pyridyl(hydroxy)methanolato-κ3O,N,N′)]iron(III) cations, with the Fe atom occupying a special position of 1̄ symmetry in each case; the Fe atom is O,N,N′-chelated by the anionic ligands in an octahedral geometry. The cation, the disordered BF4- counter-ion and the uncoordinated water molecules interact via hydrogen bonds to form a sheet motif.

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https://dspace-test.anu.edu.au/handle/1885/733741093

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DevOps Pure Testing

Source

Acta Crystallographica Section E: Structure Reports Online

Type

Article

DOI

10.1107/S1600536805002369

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Bis[di-2-pyridyl(hydroxy)methanolato-κ 3O,N,N′]-iron(I) tetrafluoroborate trihydrate

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