Syntheses and spectroscopic, structural, electrochemical, spectroelectrochemical, and theoretical studies of osmium(II) mono- and bis-alkynyl complexes
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West, Patrick
Cifuentes, Marie
Schwich, Torsten
Randles , Michael
Morrall, Joseph
Kulasekera, Erandi
Petrie, Simon
Stranger, Robert
Humphrey, Mark
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American Chemical Society
Abstract
The syntheses of trans-[Os(C≡C-4-C6H4X)Cl(dppe)2] [X = Br (3), I (4)], trans-[Os(C≡C-4-C6H4X)(NH3)(dppe)2](PF6) [X = H (5(PF6)), I (6(PF6))], and trans-[Os(C≡C-4-C6H4X)(C≡C-4-C6H4Y)(dppe)2] [X = Y = H (7), X = I, Y = C≡CSiPri3 (8)] are reported,
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Inorganic Chemistry
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2037-12-31
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