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The rearrangement of some epoxy podocarpanoic acids

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Date

1977

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Abstract

Rearrangement of the epoxides derived from the podocarpenoic acids (3b), (3d) and (5b) with boron trifluoride etherate gave compounds with the rosane skeleton, lacking substituents at C 13. The rearrangement involves the shift of a methyl group with concomitant lactonization. The unsaturated acids (3b) and (5b) undergo similar rearrangements when they are treated with boron trifluoride etherate or sulphuric acid.

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https://dspace-test.anu.edu.au/handle/1885/733739340

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DevOps Pure Testing

Source

Australian Journal of Chemistry

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Article

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DOI

10.1071/CH9771093

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