Chemistry of polynuclear compounds. Part IV. Some amine-substituted mercury halide-iron carbonyl compounds

Abstract

A number of stable derivatives of bis(chloromercury)-tetracarbonyliron with primary, secondary, and heterocyclic amines have been prepared. Replacement of one or two carbonyl groups may occur, depending upon the amine employed, to give six-co-ordinate complexes of iron. The compounds are non-electrolytes in nitrobenzene, and their infrared spectra are reported. Show more