N-(4-Chlorobutanoyl)-N′-phenylthiourea

Abstract

The asymmetric unit of the title compound, C11H 13ClN2OS, contains two independent molecules. Both molecules maintain a transcis configuration with respect to the position of the carbonyl group and the benzene ring against the thione group across the C -N bonds. The molecules are stabilized by intramolecular N -H⋯O hydrogen bonds. In the crystal, the molecules are linked by intermolecular N -H⋯S, N -H⋯O and C -H⋯S hydrogen bonds into chains along the c axis. C -H⋯π interactions further stabilize the crystal structure. Show more