Synthesis and electrochemistry of [Pt(tame)2 ]4+:  crystallographic analysis of bis [1,1,1-tris(aminomethyl)ethane-N,N]platinum(II) bis (tetrachlorozincate) dihydrate

Brown, Kylie; Hockless, David; Sargeson, Alan

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Synthesis and electrochemistry of [Pt(tame)2 ]4+: crystallographic analysis of bis [1,1,1-tris(aminomethyl)ethane-N,N]platinum(II) bis (tetrachlorozincate) dihydrate

Date

1999

Authors

Brown, Kylie

Hockless, David

Sargeson, Alan

Publisher

Royal Society of Chemistry

Abstract

Reaction of K2PtCl6 with the tripodal ligand tame [1,1,1-tris(aminomethyl)ethane] in dimethylformamide catalysed by K2PtCl4 afforded the octahedral bis(tridentate ligand) [Pt(tame)2]4+ ion. The cyclic voltammogram of [Pt(tame)2]4+ in aqueous media showed

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http://hdl.handle.net/1885/91846

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Dalton Transactions

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Journal article

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Synthesis and electrochemistry of [Pt(tame)2 ]4+: crystallographic analysis of bis [1,1,1-tris(aminomethyl)ethane-N,N]platinum(II) bis (tetrachlorozincate) dihydrate

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