Embracing ligands. Synthesis, characterisation and the correlation between  59 Co and NMR and ligand field parameters of Co(III) complexes with a new class of nitrogen-thioether multidentate ligand

Sharrad, Clint; Cavigliasso, German; Stranger, Robert; Gahan, Lawrence

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Embracing ligands. Synthesis, characterisation and the correlation between 59 Co and NMR and ligand field parameters of Co(III) complexes with a new class of nitrogen-thioether multidentate ligand

Date

2004

Authors

Sharrad, Clint

Cavigliasso, German

Stranger, Robert

Gahan, Lawrence

Publisher

Royal Society of Chemistry

Abstract

The syntheses of the hexadentate ligands 2,2,10,10-tetra(methyleneamine)-4,8-dithiaundecane (PrN4S2amp), 2,2,11,11-tetra(methyleneamine)-4,9-dithiadodecane (BuN4S2amp), and 1,2-bis(4,4-methyleneamine)-2-thiapentyl)benzene (XyN4S2amp) are reported and the

Keywords

Keywords: Absorption spectroscopy; Amines; Calculations; Characterization; Complexation; Nuclear magnetic resonance spectroscopy; Probability density function; Single crystals; Synthesis (chemical); X ray crystallography; Cobalt complexes; Hexadentate ligands; Liga

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http://hdl.handle.net/1885/86460

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Open Access Research

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Dalton Transactions

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Journal article

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Embracing ligands. Synthesis, characterisation and the correlation between 59 Co and NMR and ligand field parameters of Co(III) complexes with a new class of nitrogen-thioether multidentate ligand

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