Self-assembly of M4L4 tetrahedral cages incorporating pendant PS and PSe functionalised ligands

Butler, Patrick W.V.; Kruger, Paul E.; Ward, Jas S.

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Self-assembly of M4L4 tetrahedral cages incorporating pendant PS and PSe functionalised ligands

Date

2019

Authors

Butler, Patrick W.V.

Kruger, Paul E.

Ward, Jas S.

Abstract

Herein, the synthesis of metal-organic tetrahedral cages featuring flexible thio- and selenophosphate-based ligands is described. The cages were prepared by sub-component self-assembly of AP(OC6H4NH2-4)3 (A = S, Se) or SP(SC6H4NH2-4)3, 2-pyridinecarboxaldehyde, and either Fe[BF4]2 or Co[BF4]2. Preliminary host-guest studies into the ability of the pendant PS and PSe groups to interact with suitable substrates will be discussed.

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https://dspace-test.anu.edu.au/handle/1885/733754895

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DevOps Pure Testing

Source

Chemical Communications

Type

Article

DOI

10.1039/c9cc05443j

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Self-assembly of M4L4 tetrahedral cages incorporating pendant PS and PSe functionalised ligands

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