Metallaoxetene formation by coupling of carbamoyl and difluorocarbene ligands

Anderson, Stephen; Hill, Anthony F.; Slawin, Alexandra M.Z.; Williams, David J.

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Metallaoxetene formation by coupling of carbamoyl and difluorocarbene ligands

Date

1993

Authors

Anderson, Stephen

Hill, Anthony F.

Slawin, Alexandra M.Z.

Williams, David J.

Abstract

The reaction of the carbamoyl complex [Fe{C(=O)NPri 2}CF3(CO)2(PPh3)] with potassium hydrotris(pyrazo-1-yl)borate provides the structurally characterized ferraoxetene[Fe{CF2OC(NPri2)}(CO){HB(pz) 3}](pz=pyrazol-1-yl), presumably via coupling of the carrbamoyl of the carbammoyl ligand with a difluorocarbene intermediate.

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https://dspace-test.anu.edu.au/handle/1885/733730258

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DevOps Pure Testing

Source

Chemical Communications

Type

Article

DOI

10.1039/C39930000266

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Metallaoxetene formation by coupling of carbamoyl and difluorocarbene ligands

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