Coupling of Cyclometalated Phenylphosphanes in Dinuclear Gold(II)‐Complexes

Bennett, Martin A.; Bhargava, Suresh K.; Griffiths, K. David; Robertson, Glen B.

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Coupling of Cyclometalated Phenylphosphanes in Dinuclear Gold(II)‐Complexes

Date

1987

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Abstract

CC‐linkage of two o‐phenylene ligands was observed in the isomerization of the dinuclear gold(II) complex 1, X = I or Br, to 2. An unusual feature of this rearrangement is that the product remains fixed via the P‐donor atoms in the coordination sphere of the metal atoms.—1 is obtained from 1a (see previous communication). (Figure Presented.)

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https://dspace-test.anu.edu.au/handle/1885/733744128

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DevOps Pure Testing

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Angewandte Chemie - International Edition

Type

Article

DOI

10.1002/anie.198702601

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Coupling of Cyclometalated Phenylphosphanes in Dinuclear Gold(II)‐Complexes

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