Bond dissociation energies and radical stabilization energies associated with substituted methyl radicals

Henry, David; Parkinson, Christopher; Mayer, Paul; Radom, Leo

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Bond dissociation energies and radical stabilization energies associated with substituted methyl radicals

Date

2001

Authors

Henry, David

Parkinson, Christopher

Mayer, Paul

Radom, Leo

Publisher

American Chemical Society

Abstract

Bond dissociation energies (BDEs) and radical stabilization energies (RSEs) associated with a series of 22 monosubstituted methyl radicals (·CH2X) have been determined at a variety of levels including, CBS-RAD, G3(MP2)-RAD, RMP2, UB3-LYP and RB3-LYP. In