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Chloride triggered reversible switching from a metallosupramolecular [Pd2L4]4+ cage to a [Pd2L2Cl4] metallo-macrocycle with release of endo- and exo-hedrally bound guests

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Date

2015-05-28

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Abstract

A metallosupramolecular [Pd2L4]4+ cage can be cleanly converted into a [Pd2L2Cl4] metallo-macrocycle upon addition of chloride ions. The process is reversible, treatment of the [Pd2L2Cl4] macrocycle with silver(i) ions regenerates the [Pd2L4]4+ cage. Additionally, it is shown that guest molecules could be released on chloride triggered cage dis-assembly and taken up anew on re-assembly.

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https://dspace-test.anu.edu.au/handle/1885/733754473

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DevOps Pure Testing

Source

Chemical Communications

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Article

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DOI

10.1039/c5cc02226f

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