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Spin-orbit interactions between Rydberg states of O2

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Date

1996

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Abstract

Spin-orbit interactions between Rydberg states of O2 have been studied by observing the photoabsorption spectrum in the 1100 - 1200 Å region. The dominant interactions are between states having the same primary molecular orbital configuration and these give rise to perturbations in rotational-level structures and the appearance of nominally-forbidden absorption bands. Three examples are given showing the effects of 3Πu-1Πu and 3Σ+u-3Σ- u interactions in the ground-state absorption spectrum.

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https://dspace-test.anu.edu.au/handle/1885/733728965

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DevOps Pure Testing

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Journal of Electron Spectroscopy and Related Phenomena

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Article

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DOI

10.1016/0368-2048(96)02892-7

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