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Bidentate chelate complexes of palladium(II) with the carbanion 2-C 6 F 4 PPh 2 and their transformation into complexes containing bridging 2-C 6 F 4 PPh 2

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Bennett, Martin
Kar, Gopa
Mirzadeh, Nedaossadat
Priver, Steven H
Rae, A David
Wagler, Jorg
Willis, Anthony
Bhargava, Suresh Kumar

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American Chemical Society

Abstract

Reaction of the organotin compound 2-Me3SnC6F 4PPh2 (7) with the cycloocta-1,5-diene complexes [PdX 2(cod)] at room temperature gives dinuclear halide-bridged palladium(II) complexes [Pd2(μ-X)2(κ2- 2-C6F4PPh2)2] [X = Cl (5), Br (8)] in which the carbani

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Organometallics

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Restricted until

2037-12-31