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Formation of unsymmetrical cis-dialkyls of platinum(II) from platinum(II) hydroxo-complexes

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1973-07-16

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Abstract

The (hydroxo) methyl complex Pt(OH)(CH3)(Diphos) [Diphos = Ph2PCH2CH2PPh2] reacts with compounds containing acidic CH bonds (HX) to give unsymmetrical cis-dialkyls of general formula Pt(CH3)X(Diphos) [X = CH2COCH3, CH(COCH3)2, CH2CN or CH2NO2]; both the methyl and the cyclohexenyl complexes Pt(OH)R(Diphos) (R = CH3 or C6H9) insert carbon monoxide to give hydroxycarbonyl complexes PtR(CO2H)(Diphos) which are remarkably stable to decomposition by β-elimination.

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https://dspace-test.anu.edu.au/handle/1885/733743891

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DevOps Pure Testing

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Journal of Organometallic Chemistry

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Article

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DOI

10.1016/S0022-328X(00)82057-4

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