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Chelate Mn-C and Re-C σ-bonded complexes formed by hydrometallation of an olefinic tertiary phosphine

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Date

1971

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Abstract

The complex hydrides formed by o-styryldiphenylphosphine (sp), HM(CO) 4(sp) (M = Mn or Re), rapidly undergo intramolecular hydride addition to the free vinyl group of the ligand giving stable chelate M-C σ-bonded complexes, the direction of addition being predominantly Markownikoff in the case of manganese and anti-Markownikoff in the case of rhenium.

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Citation

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https://dspace-test.anu.edu.au/handle/1885/733733382

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DevOps Pure Testing

Source

Journal of the Chemical Society D: Chemical Communications

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Article

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DOI

10.1039/C29710000094

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