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Formation of metallaboratranes

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2005-03-14

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Abstract

The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-boron bond is supported by only two methimazolyl buttresses.

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https://dspace-test.anu.edu.au/handle/1885/733717869

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DevOps Pure Testing

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Organometallics

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Article

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DOI

10.1021/om040128f

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