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Arene-olefin complexes of zerovalent iron and ruthenium

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Convenient syntheses of arene-olefin complexes of iron(0) and ruthenium(0), e.g. M(η6-C6Me6)(η4-diene) (M = Fe, Ru, diene = 1,3-cyclohexadiene or 1,5-cyclooctadiene), Fe(η6-C6Me6)(η4-C7H8) (C7H8 = 1,3,5-cycloheptatriene) and Ru(η6-C6Me6)(C2H4)2 are given, and some protonation reactions are described.

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Journal of Organometallic Chemistry

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