Reactions of transition metal σ-acetylide complexes. xiii

Bruce, Michael I.; Humphrey, Mark G.

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Reactions of transition metal σ-acetylide complexes. xiii

Date

1989

Authors

Bruce, Michael I.

Humphrey, Mark G.

Abstract

A series of 20 cationic vinylidene complexes of ruthenium and osmium [M(CCRR')(L)(L')(-C5H5)]+ (R = Me, Ph, C6H4F-4, C6F5, (CH2)2C2H; R'=Me, CH2Ph, CH2CH=CH2, CH2C≡CH, (CH2)Br; L, L' = PPh3, CNBUt, dppm, dppe; not all combinations), [(Ru(CCRCH2-)(PPh3)2(-C5H5))2]2+ and [CH2(CPhCRu(PPh3)2(-C5H5))2]2+ have been obtained from reactions between the metal acetylide complexes and the appropriate organic halides.

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https://dspace-test.anu.edu.au/handle/1885/733728159

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DevOps Pure Testing

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Australian Journal of Chemistry

Type

Article

DOI

10.1071/CH9891067

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Reactions of transition metal σ-acetylide complexes. xiii

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