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Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to C=C, C=O, and C=S Double Bonds

Date

Authors

Henry, David

Coote, Michelle

Gomez-Balderas, Rodolfo

Radom, Leo

Publisher

American Chemical Society

Abstract

The barriers, enthalpies, and rate constants for the addition of methyl radical to the double bonds of a selection of alkene, carbonyl, and thiocarbonyl species (CH2=Z, CH3CH=Z, and (CH 3)2C=Z, where Z = CH2, O, or S) and for the reverse β-scission react

Keywords

Keywords: Chemical bonds; Enthalpy; Mathematical models; Olefins; Phase transitions; Rate constants; Substrates; Contrathermodynamic reactions; Reaction barriers; Methanol; alkene; carbon; carbonyl derivative; methyl group; oxygen; radical; sulfur; thiocarbonyl der

URI

http://hdl.handle.net/1885/86414

Collections

Open Access Research

Source

Journal of the American Chemical Society

Type

Journal article

DOI

10.1021/ja039139a

Restricted until

2037-12-31

Downloads

File

Description

01_Henry_Comparison_of_the_Kinetics_and_2004.pdf (119.64 KB)