(2,2'-Bipyridine-κ2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ2 S,S')zinc(II)
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The complete molecule of the title compound, [Zn(C4H 8NS2)2(C10H8N 2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C - C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.
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Abdul Ghafar, N A, Baba, I, Yamin, B M & Ng, S W 2010, '(2,2'-Bipyridine-κ 2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ 2 S,S')zinc(II)', Acta Crystallographica Section E: Structure Reports Online, vol. 66, no. 2, pp. m208. https://doi.org/10.1107/S1600536810002606
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Acta Crystallographica Section E: Structure Reports Online