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4-Alkoxycarbonyl- and aminocarbonyl-substituted isoxazoles as masked acrylates and acrylamides in the asymmetric synthesis of Δ 2 -isoxazolines

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Date

2006

Authors

Lee, Connie
Herlt, Anthony
Simpson, Gregory Wayne
Willis, Anthony
Easton, Christopher

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

4-Alkoxycarbonyl and aminocarbonyl-substituted isoxazoles undergo conjugate reduction to give Δ2-isoxazolines on treatment with sodium borohydride and sodium trifluoroacetoxyborohydride, respectively. They are also alkylated at C5 through sonication with

Description

Keywords

Keywords: Acrylamides; Soxazolines; Tertiary alkyl iodides; Alkylation; Reaction kinetics; Reduction; Sodium compounds; Substitution reactions; Synthesis (chemical); Organic compounds; acrylamide derivative; acrylic acid derivative; aminocarbonyl derivative; carbon

Citation

URI

http://hdl.handle.net/1885/83018

Collections

Open Access Research

Source

Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/jo0602569

Restricted until

2037-12-31

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Description
01_Lee_4-Alkoxycarbonyl-_and_2006.pdf (214.82 KB)

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