Orientational dependences of the Zeeman effect in the lowest-excited states of [Zn(bpy)3](ClO4)2:Ru(II) and [Ru(bpy)3](PF6)2

Riesen, H.; Krausz, E.

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Orientational dependences of the Zeeman effect in the lowest-excited states of [Zn(bpy)3](ClO4)2:Ru(II) and [Ru(bpy)3](PF6)2

Date

1994-01-28

Authors

Riesen, H.

Krausz, E.

Abstract

The positions and intensities of the electronic origins in [Zn(bpy)3](ClO4)2:Ru(II) are strongly dependent on the orientation of an applied magnetic field within the metal-ligand plane. Spectra can be calculated by a model in which the lowest-energy charge-transfer excitations involve an individual metal-ligand subunit. The model can also reproduce all the significant features of the spectra reported for [Ru(bpy)3](PF6)2.

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https://dspace-test.anu.edu.au/handle/1885/733740313

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DevOps Pure Testing

Source

Chemical Physics Letters

Type

Article

DOI

10.1016/0009-2614(93)E1420-L

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Orientational dependences of the Zeeman effect in the lowest-excited states of [Zn(bpy)3](ClO4)2:Ru(II) and [Ru(bpy)3](PF6)2

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