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Temperature dependence of Raman scattering from the high-pressure phases of Si induced by indentation

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Johnson, Brett
Haberl, Bianca
Bradby, Jodie
McCallum, Jeffrey C
Williams, James

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American Physical Society

Abstract

A micro-Raman scattering study on the linewidth and frequency shift of Si-III and Si-XII produced by indentation is presented over the temperature range 80-300 K. Measurements are compared to the Raman lines originating from the Si-I substrate. The main Si-XII Raman line shows a strong dependence on temperature and can be adequately described by anharmonic terms from the phonon proper self-energy. In contrast, the main Si-III Raman linewidth decreases with increasing temperature. A model related to electron-phonon interactions describes the data well.

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Physical Review B: Condensed Matter and Materials

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