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Synthesis, structures and dynamic NMR spectra of η 6 -hexaethylbenzene complexes of ruthenium(0) and ruthenium(II).

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Date

2002

Authors

Baldwin, Richard
Bennett, Martin
Hockless, David
Pertici, Paolo
Verrazzani, Alessandra
Barretta, Gloria
Marchetti, Fabio
Salvadori, Piero

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

On reaction with the labile naphthalene complex [Ru(η6-C10H8)(η4-1, 5-COD)], hex-3-yne undergoes stoichiometric cyclotrimerisation to form the hexaethylbenzene-ruthenium(O) complex [Ru(η6-C6Et6)(η4-1, 5-COD)] 1. In the solid state and in solution the

Description

Keywords

Keywords: Band structure; Benzene; Chemical bonds; Complexation; Conformations; Crystal structure; Crystalline materials; Electrolytes; Infrared spectroscopy; Nuclear magnetic resonance spectroscopy; Solutions; Synthesis (chemical); Arene metal bond; Crystalline ad

Citation

URI

http://hdl.handle.net/1885/72522

Collections

Open Access Research

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b204875m

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