Porphyrin dimers linked by conjugated butadiyne bridges: preparations, spectra, voltammetry and reductive spectroelectrochemistry of {[M(OEP)](m-C4)[M(OEP)]} (M2 � H4, Co2, Ni2, Cu2, Zn2, Pd2, Pt2, Co/Ni, Ni/Cu, Ni/Zn)

Arnold, Dennis; Heath, Graham; James, Dionne

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Porphyrin dimers linked by conjugated butadiyne bridges: preparations, spectra, voltammetry and reductive spectroelectrochemistry of {[M(OEP)](m-C4)[M(OEP)]} (M2 � H4, Co2, Ni2, Cu2, Zn2, Pd2, Pt2, Co/Ni, Ni/Cu, Ni/Zn)

Date

1999

Authors

Arnold, Dennis

Heath, Graham

James, Dionne

Publisher

John Wiley & Sons Inc

Abstract

A series of derivatives M2P2 (M2 ≡ H4, Co2, Ni2, Cu2, Zn2, Pd2, Pt2, Co/Ni, Ni/Cu, Ni/Zn) of the ligand meso,meso′-bis(octaethylporphyrinyl)butadiyne has been prepared and characterized by 1H NMR, FT Raman and visible absorption spectroscopies as well

Keywords

Keywords: Dimer; Frontier orbitals; Mixed valency; Porphyrin; Spectroelectrochemistry; Spectroscopy; Voltammetry

URI

http://hdl.handle.net/1885/93739

Collections

Open Access Research

Source

Journal of Porphyrins and Phthalocyanines

Type

Journal article

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Cultural advice

Porphyrin dimers linked by conjugated butadiyne bridges: preparations, spectra, voltammetry and reductive spectroelectrochemistry of {[M(OEP)](m-C4)[M(OEP)]} (M2 � H4, Co2, Ni2, Cu2, Zn2, Pd2, Pt2, Co/Ni, Ni/Cu, Ni/Zn)

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