Studies on intramolecular alkylation. IX the synthesis of tricyclic dienones suitable for the synthesis of 13-hydroxygibberellins

Blair, Ian A.; Ellis, Andrea; Johnson, David W.; Mander, Lewis N.

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Studies on intramolecular alkylation. IX the synthesis of tricyclic dienones suitable for the synthesis of 13-hydroxygibberellins

Date

1978

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Abstract

2- Hydroxy-6-methoxy-l, 2, 3, 4-tetrahydro-2-naphthoic acid and its 8-methoxy isomer were converted into trichloroacetate and dichloroacetate derivatives and thence to diazoketones (2), (3), (12) and (13). The acid-catalysed cyclization of these substrates to the dienones (6), (7), (16) and (17), respectively, was then studied. The trichloroacetoxy derivatives gave the best yields of dienones.

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https://dspace-test.anu.edu.au/handle/1885/733728106

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DevOps Pure Testing

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Australian Journal of Chemistry

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Article

DOI

10.1071/CH9780405

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Studies on intramolecular alkylation. IX the synthesis of tricyclic dienones suitable for the synthesis of 13-hydroxygibberellins

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