Highly fluxional tetrahapto-cyclooctatetraene complexes of ruthenium(0)

Bennett, M. A.; Matheson, T. W.; Robertson, G. B.; Smith, A. K.; Tucker, P. A.

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Highly fluxional tetrahapto-cyclooctatetraene complexes of ruthenium(0)

Date

1976-11-23

Authors

Abstract

In complexes of the type Ru(arene)(cot) (cot = cyclooctatetraene) the cyclooctatetraene ring is 1-4-η-bonded as shown by X-ray diffraction study of the hexamethylbenzene derivative, and the barrier to intramolecular exchange of the bound and unbound halves of the eight-membered ring is unusually low (< 6 kcal/mol).

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https://dspace-test.anu.edu.au/handle/1885/733740173

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DevOps Pure Testing

Source

Journal of Organometallic Chemistry

Type

Article

DOI

10.1016/S0022-328X(00)80777-9

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Highly fluxional tetrahapto-cyclooctatetraene complexes of ruthenium(0)

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