Five-Coordinate Hydrido-Ruthenium(II) Complexes Featuring  N -Heterocyclic Silylene and Carbene Ligands

Cade, Ian; Hill, Anthony; Kamphe, Alex; Wagler, Jorg

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Five-Coordinate Hydrido-Ruthenium(II) Complexes Featuring N -Heterocyclic Silylene and Carbene Ligands

Date

2010

Authors

Cade, Ian

Hill, Anthony

Kamphe, Alex

Wagler, Jorg

Publisher

American Chemical Society

Abstract

The reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H2)(PCy3)2] and IiPr.

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http://hdl.handle.net/1885/60513

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Open Access Research

Source

Organometallics

Type

Journal article

DOI

10.1021/om100146m

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2037-12-31

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Five-Coordinate Hydrido-Ruthenium(II) Complexes Featuring N -Heterocyclic Silylene and Carbene Ligands

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