Test environment running 7.6.6

Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Bis(acetylacetonato)ruthenium(II) complexes containing bulky tertiary phosphines. Formation and redox behaviour of Ru(acac) 2 (PR 3 ) (R = i Pr, Cy) complexes with ethene, carbon monoxide, and bridging dinitrogen

Thumbnail Image

Date

2005

Authors

Bennett, Martin
Byrnes, Matthew
Chung, Guandolina
Edwards, Alison
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

Reaction of cis-[Ru(acac)2(η2-C8H 14)2] (1) (acac = acetylacetonato) with two equivalents of PiPr3 in THF at -25°C gives trans-[Ru(acac) 2(PiPr3)2], trans-3, which rapidly isomerizes to cis-3 at room temperature. The poorly soluble complex [Ru(acac)2(PC

Description

Keywords

Keywords: benzene; carbon monoxide; ethylene; nitrous oxide; phosphine derivative; ruthenium complex; toluene; article; chemical reaction kinetics; complex formation; crystal structure; cyclic potentiometry; electrochemistry; isomerization; oxidation; oxidation red Acetylacetonato complex; Redox behaviour; Ruthenium (II) complex; X-ray crystal structure

Citation

URI

http://hdl.handle.net/1885/82447

Collections

Open Access Research

Source

Inorganica Chimica Acta

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/j.ica.2004.07.062

Restricted until

2037-12-31

Downloads

File
Description
01_Bennett_Bis(acetylacetonato)ruthenium(I_2005.pdf (547.03 KB)

DSpace software copyright © 2002-2026 LYRASIS