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The structures of three new Galbulimima alkaloids

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Mander, Lewis
Willis, Anthony
Herlt, Anthony
Taylor, Walter C

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Elsevier

Abstract

The structures of three new alkaloids isolated from the bark of the rain forest tree Galbulimima belgraveana, have been determined by a combination of NMR spectroscopy and X-ray crystallography. One of the alkaloids, himgrine (5), was shown to be an oxygenated derivative of himbacine (1), while the second, GB16, (8) proved to be identical with a degradation product from himgaline (4). The remaining alkaloid, GB17 (12) possesses an entirely new and unexpected skeleton.

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Tetrahedron Letters

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Restricted until

2037-12-31