Chemoenzymatic and enantiodivergent routes to 1,2-ring-fused bicyclo[2.2.2]octane and related tricyclic frameworks

Austin, Kerrie A.B.; Elsworth, Jon D.; Banwell, Martin G.; Willis, Anthony C.

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Chemoenzymatic and enantiodivergent routes to 1,2-ring-fused bicyclo[2.2.2]octane and related tricyclic frameworks

Date

2010

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Abstract

New and simple protocols are described for the conversion of the enzymatically-derived and enantiomerically pure cis-1,2-dihydrocatechol 7 (X = I) and its 6-methylated derivative into either antipodal form of compounds embodying the tricyclic frameworks of terpenoids 1-6. Key steps include intramolecular Diels-Alder (IMDA) and (in some cases) singlet or triplet-based photochemical processes.

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https://dspace-test.anu.edu.au/handle/1885/733750748

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DevOps Pure Testing

Source

Organic and Biomolecular Chemistry

Type

Article

DOI

10.1039/b921600f

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Chemoenzymatic and enantiodivergent routes to 1,2-ring-fused bicyclo[2.2.2]octane and related tricyclic frameworks

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