New metabolites of the lichen Buellia canescens (dicks.) de not
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The isolation and structural determination of the lichen metabolites dechlorodiploicin (2), dechloro-O-methyldiploicin (3), buellolide (4), and canesolide (6) are described; buellolide (4) and canesolide (6) are thought to arise by catabolism of their congeneric depsidones, in the latter case with Smiles rearrangement.
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Chemical Communications