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Structural Perturbations Within Ge Nanocrystals in Silica

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Cheung, Allen
de Azevedo, Gustavo
Glover, Christopher
Llewellyn, David
Elliman, Robert
Foran, Garry J
Ridgway, Mark C

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American Institute of Physics (AIP)

Abstract

Ge nanocrystals retain the diamond-type lattice characteristic of bulk crystalline materials. However, EXAFS measurements demonstrate the presence of atomic-scale structural perturbations in Ge nanocrystals relative to bulk crystalline material. These perturbations are apparent as both bond length and bond angle distortions and attributed to the influences of interfacial-bonding-induced strain and a matrix-induced compression.

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Applied Physics Letters

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