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A tridentate unsaturated tertiary phosphine obtained by dehydrogenation of 2,2'-bis(diphenylphosphino)bibenzyl in the presence of rhodium complexes; X-ray crystal structure of the chelate olefin complex RhCl(o-Ph2P· C6H4·CH:CH·C6H 4·PPh2-o),CH2Cl2

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1972

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Abstract

The chelate olefin complex RhCl(o-Ph2P·C 6H4·CH:CH·C6H4· PPh2-o) is formed by dehydrogenation of 2,2'-bis(diphenylphosphino) bibenzyl, o-Ph2P·C6H4·CH 2·CH2·C6H4· PPh2-o, in the presence of RhI or RhIII compounds, and is shown to be essentially square planar by X-ray structural analysis; four- and five-co-ordinate iridium(I) complexes are also formed by the tridenate olefinic ligand.

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https://dspace-test.anu.edu.au/handle/1885/733734172

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DevOps Pure Testing

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Chemical Communications

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Article

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DOI

10.1039/C39720001011

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