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Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

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Date

2010

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Abstract

The heterodinuclear complexes [FeZn(L)(CH3CO2)2]+ (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases. They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases.

Description

Keywords

Bioinorganic chemistry, Dinuclear, Heterodinuclear, HPNP, Iron, Model complexes, Purple acid phosphatase, Transesterification, Zinc

Citation

URI

https://dspace-test.anu.edu.au/handle/1885/733736143

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DevOps Pure Testing

Source

Inorganic Chemistry Communications

Type

Article

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DOI

10.1016/j.inoche.2009.12.007

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