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Towards Detection of a Long-lived Protonated Metal Cation: Generation of GeH2+ Using High-Energy Collisions

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Date

2000

Authors

Jackson, Phillip
Diefenbach, Martin
Srinivas, Ragampeta
Schroder, Detlef
Schwarz, Helmut

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

A minimal lifetime of microseconds is displayed by the dication GeH2+, which has been detected for the first time as the product of charge-stripping experiments at 8 kV involving [GeH2]+ and O2. Coupled-cluster calculations suggest that XH2+ (X = Si, Ge)

Description

Keywords

Keywords: article; chemical binding; electricity; ligand binding; mass spectrometry; molecular interaction; physics Ab initio calculations; Dications; Germanium; Mass spectrometry

Citation

URI

http://hdl.handle.net/1885/89042

Collections

Open Access Research

Source

Angewandte Chemie International Edition

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/(SICI)1521-3773(20000417)39:8<1445::AID-ANIE1445>3.0.CO;2-Y

Restricted until

2037-12-31

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01_Jackson_Towards_Detection_of_a_2000.pdf (82.66 KB)

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