Test environment running 7.6.6

Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Generation of nickel(0)-aryne and nickel(II)-biphenyldiyl complexes via in situ dehydrohalogenation of arenes. Molecular structures of [Ni(2,2-C 6 H 4 C 6 H 4 )(dcpe)] and C 2 -hexabenzotriphenylene.

Thumbnail Image

Date

2003

Authors

Bennett, Martin
Kopp, Mikchael
Wenger, Eric
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

Reactions of the aromatic halides chlorobenzene, 9-bromophenanthrene and chloro-p-xylene with lithium 2,2,6,6-tetramethylpiperidide (LiTMP) in the presence of [Ni(η2-C2H4)(dcpe)] (1) generated the corresponding η2-aryne complexes [Ni(η2-aryne)(dcpe)] [

Description

Keywords

Keywords: chlorobenzene; halide; lithium derivative; nickel complex; phenanthrene derivative; polycyclic aromatic hydrocarbon derivative; xylene; chemical reaction; chemical structure; complex formation; controlled study; halogenation; isolation procedure; review; Aryne complex; Cyclotrimerisation; Dehydrohalogenation; Insertion reaction; Nickel

Citation

URI

http://hdl.handle.net/1885/94247

Collections

Open Access Research

Source

Journal of Organometallic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/S0022-328X(02)01667-4

Restricted until

DSpace software copyright © 2002-2026 LYRASIS