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Hydrothermal synthesis of chiral metal(II) phosphinates derived from camphor

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Date

2009

Authors

Beckmann, Jens
Duthie, Andrew
Ruttinger, Roman
Schwich, Torsten

Journal Title

Journal ISSN

Volume Title

Publisher

Walter de Gruyter

Abstract

The diastereoselective synthesis of bis(3-endo-camphoryl)phosphinic acid (1) and its 2-bornen-2-yl ester 2 from the reaction of lithium camphor enolate with phosphorus trichloride and the hydrothermal synthesis of three chiral molecular metal(II) phosphinates of the type M(O2PR2) 2.2R2P(O)OH [M = Co (3); Ni (4); Pb (5); R = 3-endo-camphoryl] from the reaction of 1 with metal(II) acetates or nitrates is described. The molecular structures of 1-5 are reported.

Description

Keywords

Citation

URI

http://hdl.handle.net/1885/80107

Collections

Open Access Research

Source

Zeitschrift fuer Anorganische und Allgemeine Chemie

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/zaac.200900065

Restricted until

2037-12-31

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