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HPHT synthesis of large single crystal diamond doped with high nitrogen concentration

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Date

2008

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Abstract

Large green single crystal diamond with high nitrogen concentration is firstly synthesized by temperature gradient method under high pressure and high temperature (HPHT). Sodium azide (NaN3) is added as the source of nitrogen to the synthesis system of high pure graphite and kovar alloy (Fe59Co25Ni17). The HPHT synthesis condition is 5.4 GPa and 1480 K. The maximum crystal size is 3.2 mm. The infrared absorption spectra indicate that the nitrogen concentration in the green large single crystal diamond reaches 1520 ppm in the form of single substitution, which is close to that in nature diamond, and several times higher than that in the man-made Ib large single crystal diamond previously.

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Keywords

High nitrogen concentration, HPHT, Single crystal diamond, Synthesis

Citation

URI

https://dspace-test.anu.edu.au/handle/1885/733745743

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DevOps Pure Testing

Source

Diamond and Related Materials

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Article

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DOI

10.1016/j.diamond.2007.12.018

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