Dinitrogen and related chemistry of the lanthanides

Gardiner, Michael G.; Stringer, Damien N.

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Dinitrogen and related chemistry of the lanthanides

Date

2010

Authors

Gardiner, Michael G.

Stringer, Damien N.

Abstract

This paper reviews the current array of complexes of relevance to achieving lanthanide mediated nitrogen fixation. A brief history of nitrogen fixation is described, including a limited discussion of successful transition metal facilitated nitrogen fixation systems. A detailed discussion of the numerous lanthanide-nitrogen species relevant to nitrogen fixation are discussed and are related to the Chatt cycle for nitrogen fixation.