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Separated and aligned molecular fibres in solid state self-assemblies of cyclodextrin [2]rotaxanes

Date

Authors

Onagi, Hideki

Carrozzini, Benedetta

Cascarano, Giovanni

Easton, Christopher

Edwards, Alison

Lincoln, Stephen F

Rae, A David

Publisher

Wiley-VCH Verlag GMBH

Abstract

The conformations of two [2]rotaxanes, each comprising α -cyclodextrin as the rotor, a stilbene as the axle and 2,4,6-trinitrophenyl substituents as the capping groups, have been examined in solution and in the solid state, using1H NMR spectroscopy and X

Keywords

Keywords: Aromatic compounds; Nuclear magnetic resonance spectroscopy; Self assembly; Solutions; Substitution reactions; X ray crystallography; Capping groups; Molecular fibers; Molecular dynamics; alpha cyclodextrin; cyclodextrin derivative; rotaxane; stilbene; tr Cyclodextrins; Nanostructures; Rotaxanes; Self-assembly; Supramolecular chemistry

URI

http://hdl.handle.net/1885/86030

Collections

Open Access Research

Source

Chemistry, A European Journal

Type

Journal article

DOI

10.1002/chem.200305279

Restricted until

2037-12-31

Downloads

File

Description

01_Onagi_Separated_and_aligned_2003.pdf (326.08 KB)