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Intermolecular Casimir-Polder forces in water and near surfaces

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Authors

Thiyam, P.
Persson, Clas
Sernelius, B
Parsons, Drew
Malthe-Sorenssen, Anders
Bostrom, Mathias

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American Physical Society

Abstract

The Casimir-Polder force is an important long-range interaction involved in adsorption and desorption of molecules in fluids. We explore Casimir-Polder interactions between methane molecules in water, and between a molecule in water near SiO2 and hexane surfaces. Inclusion of the finite molecular size in the expression for the Casimir-Polder energy leads to estimates of the dispersion contribution to the binding energies between molecules and between one molecule and a planar surface.

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Physical Review E-Statistical, Nonlinear and Soft Matter Physics

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Restricted until

2037-12-31