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On the hydrogen-induced corrosion of AISI 410

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The martensitic stainless steel (SS) AISI 410 is prone to sulphide stress cracking (SSC) in "sour" service, such as H2S environments, due to hydrogen (H) embrittlement. The presence of absorbed H within SS makes them more susceptible to pitting, corrosion and environmentally assisted cracking, however the mechanistic aspects of such H-induced corrosion has not been fully elucidated in research to date. Herein, a zero resistance ammeter (ZRA) was used to investigate the impact of absorbed H on the corrosion of AISI 410, by galvanically coupling H-charged and uncharged SS specimens. A mechanism of H-induced corrosion was proposed based on the evidence of hydrogen oxidation, metal dissolution and passive film reduction from the H-charged specimens during such ZRA tests.

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